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Multi-Collector
ICP-MS

The Nu Plasma High Resolution
Multi-Collector
ICP Mass Spectrometer (Nu
Instruments
Inc.) at the UCD Center features a double focusing Nier Johnson
design. With this approach, compensation of the ion beam energy spread
leads to a high quality image. The mass spectrometer comprises an
electrostatic analyser (ESA) followed by a magnetic sector. Unique to
the Nu Plasma are the quadrupole lenses placed between the magnet and
Faraday collector array that can act as a zoom lens to alter the
dispersion of the instrument thus removing the necessity for movable
collectors. The Nu Plasma can be used for either solution
or solid
sampling.

The standard mass resolution of a typical modern high precision mass
spectrometer such as Nu Plasma is approximately 400. At this
resolution, the instrument produces flat top peaks that are essential
for high precision isotopic measurements whole maintaining a good
sensitivity. For many elements, molecular species can be generated
which can cause interferences on the mass spectrum. These can become a
problem for accurate isotopic ratio determination. The Nu Plasma at the
UCD Center is equipped with two high resolution modes: pseudo-high
(partial) resolution (if the interferences are on the same side of the
peak), and high resolution. With a compromise in sensitivity by a
factor of 10 typically, a mass resolution of 8000 could be achieved,
therefore certain interfering molecular species could be resolved from
the isotope peak of interest.
To achieve accurate and precise isotope ratio measurements good
instrument abundance sensitivity is essential. This ensures that the
tailing of large isotopes do not impinge on smaller adjacent isotopes
causing inaccurate isotope ratio measurements. The analyzer vacuum of
the Nu Plasma is maintained at 2E-9 mbar supported by three ion pumps,
which is essential to remove tailing effect. Typical abundance
sensitivity of the Nu Plasma is 4ppm at -1amu. With the retardation
lens filter, 500ppb (-1amu) and 50 ppb (-2amu) are further achieved.
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